4-Bromo-3-methylanilinium hydrogen sulfate
نویسنده
چکیده
In the cation of the title compound, C(7)H(9)BrN(+)·HSO(4) (-), the amino N atom is protonated. In the crystal, inter-molecular O-H⋯O and N-H⋯O hydrogen bonds generate an infinite two-dimensional network parallel to (001).
منابع مشابه
4-Bromo-3-methylanilinium perchlorate
In the title compound, C(7)H(9)BrN(+)·ClO(4) (-), the cations and anions are linked by inter-molecular N-H⋯O hydrogen bonds, forming a two-dimensional network parallel to the ab plane.
متن کامل4-Bromo-3-methylanilinium perchlorate 18-crown-6 clathrate
The reaction of 4-bromo-3-methyl-anilinium perchlorate and 18-crown-6 in methanol solution yielded the title compound, C(7)H(9)BrN(+)·ClO(4) (-)·C(12)H(24)O(6). The protonated 4-bromo-3-methyl-amine unit contains one -NH(3) (+) substituent, resulting in a 1:1 supra-molecular rotator-stator structure, (C(7)H(9)Br-NH(3) (+))(18-crown-6), through three bifurcated N-H⋯(O,O) hydrogen bonds between t...
متن کاملBis(3-methylanilinium) sulfate
In the crystal structure of the title salt, 2C(7)H(7)NH(3) (+)·SO(4) (2-), the cations inter-act with the oxyanions through strong charge-assisted N-H⋯O hydrogen bonds.
متن کامل3-Methylanilinium hydrogen phthalate
The asymmetric unit of the title salt, C(7)H(10)N(+)·C(8)H(5)O(4) (-), consists of two 3-methyl-phenyl-ammonium cations and two hydrogen phthalate anions. There are strong intra-molecular O-H⋯O hydrogen bonds in the virtually planar (r.m.s. deviations = 0.054 Å) phthalate anions. In the crystal, the cations and anions are connected via an extensive sytem of N-H⋯O hydrogen bonds into a corrugate...
متن کامل4-Methylanilinium p-toluenesulfonate
The crystal structure of the title compound, C(7)H(10)N(+)·C(7)H(7)O(3)S(-), displays strong N-H⋯O and N-H⋯S hydrogen bonding between the ammonium group and the p-toluene-sulfonate anion, linking the cations and anions into chains along the b axis.
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